The Potentiometer
Suppose you wish to measure the emf of a battery. Consider what happens if you connect the battery directly to a standard voltmeter as shown in Figure 4.37. Once we note the problems with this measurement, we will examine a null measurement that improves accuracy. As discussed before, the actual quantity measured is the terminal voltage which is related to the emf of the battery by where is the current that flows and is the internal resistance of the battery.
The emf could be accurately calculated if were very accurately known, but it is usually not. If the current could be made zero, then so emf could be directly measured. However, standard voltmeters need a current to operate; thus, another technique is needed.
A potentiometer is a null measurement device for measuring potentials (voltages) (see Figure 4.38). A voltage source is connected to a resistor say, a long wire, and passes a constant current through it. There is a steady drop in potential (an drop) along the wire so that a variable potential can be obtained by making contact at varying locations along the wire.
Figure 4.38(b) shows an unknown (represented by script in the figure) connected in series with a galvanometer. Note that opposes the other voltage source. The location of the contact point (see the arrow on the drawing) is adjusted until the galvanometer reads zero. When the galvanometer reads zero, where is the resistance of the section of wire up to the contact point. Since no current flows through the galvanometer, none flows through the unknown emf, so is directly sensed.
Now, a very precisely known standard is substituted for and the contact point is adjusted until the galvanometer again reads zero so that In both cases, no current passes through the galvanometer, so the current through the long wire is the same. Upon taking the ratio cancels, giving
4.71
Solving for gives
4.72
Because a long uniform wire is used for the ratio of resistances is the same as the ratio of the lengths of wire that zero the galvanometer for each emf. The three quantities on the right-hand side of the equation are now known or measured, and can be calculated. The uncertainty in this calculation can be considerably smaller than when using a voltmeter directly, but it is not zero. There is always some uncertainty in the ratio of resistances and in the standard Furthermore, it is not possible to tell when the galvanometer reads exactly zero, which introduces error into both and and may also affect the current