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Electromotive Force

You can think of many different types of voltage sources. Batteries themselves come in many varieties. There are many types of mechanical/electrical generators, driven by many different energy sources, ranging from nuclear to wind. Solar cells create voltages directly from light, while thermoelectric devices create voltage from temperature differences.

A few voltage sources are shown in Figure 4.8. All such devices create a potential difference and can supply current if connected to a resistance. On the small scale, the potential difference creates an electric field that exerts force on charges, causing current. Thus, we use the name electromotive force, abbreviated emf.

Emf is not a force at all; it is a special type of potential difference. To be precise, the emf is the potential difference of a source when no current is flowing. Units of emf are volts.

Figure 4.8 A variety of voltage sources (clockwise from top left): the Brazos Wind Farm in Fluvanna, Texas (Leaflet, Wikimedia Commons); the Krasnoyarsk Dam in Russia (Alex Polezhaev); a solar farm (U.S. Department of Energy); and a group of nickel metal hydride batteries (Tiaa Monto). The voltage output of each depends on its construction and load and equals emf only if there is no load.

Electromotive force is directly related to the source of potential difference, such as the particular combination of chemicals in a battery. However, emf differs from the voltage output of the device when current flows. The voltage across the terminals of a battery, for example, is less than the emf when the battery supplies current, and it declines further as the battery is depleted or loaded down. However, if the device’s output voltage can be measured without drawing current, then output voltage will equal emf (even for a very depleted battery).

Internal Resistance

As noted before, a 12-V truck battery is physically larger, contains more charge and energy, and can deliver a larger current than a 12-V motorcycle battery. Both are lead-acid batteries with identical emf, but, because of its size, the truck battery has a smaller internal resistance $r\text{.}r\text{.}$ Internal resistance is the inherent resistance to the flow of current within the source itself.

Figure 4.9 is a schematic representation of the two fundamental parts of any voltage source. The emf (represented by a script E in the figure) and internal resistance $rr$ are in series. The smaller the internal resistance for a given emf, the more current and the more power the source can supply.

Figure 4.9 Any voltage source (in this case, a carbon-zinc dry cell) has an emf related to its source of potential difference and an internal resistance $rr$ related to its construction. (Note that the script E stands for emf.) Also shown are the output terminals across which the terminal voltage $VV$ is measured. Since $V=\text{emf}-\text{Ir}\text{,}V=\text{emf}-\text{Ir}\text{,}$ terminal voltage equals emf only if there is no current flowing.

The internal resistance $rr$ can behave in complex ways. As noted, $rr$ increases as a battery is depleted. But, internal resistance may also depend on the magnitude and direction of the current through a voltage source, its temperature, and even its history. The internal resistance of rechargeable nickel-cadmium cells, for example, depends on how many times and how deeply they have been depleted.

Things Great and Small: The Submicroscopic Origin of Battery Potential

Various types of batteries are available, with emfs determined by the combination of chemicals involved. We can view this as a molecular reaction (what much of chemistry is about) that separates charge.

The lead-acid battery used in cars and other vehicles is one of the most common types. A single cell (one of six) of this battery is seen in Figure 4.10. The cathode (positive) terminal of the cell is connected to a lead oxide plate, while the anode (negative) terminal is connected to a lead plate. Both plates are immersed in sulfuric acid, the electrolyte for the system.

Figure 4.10 Artist’s conception of a lead-acid cell. Chemical reactions in a lead-acid cell separate charge, sending negative charge to the anode, which is connected to the lead plates. The lead oxide plates are connected to the positive or cathode terminal of the cell. Sulfuric acid conducts the charge as well as participating in the chemical reaction.

The details of the chemical reaction are left to the reader to pursue in a chemistry text, but their results at the molecular level help explain the potential created by the battery. Figure 4.11 shows the result of a single chemical reaction. Two electrons are placed on the anode, making it negative, provided that the cathode supplied two electrons. This leaves the cathode positively charged because it has lost two electrons. In short, a separation of charge has been driven by a chemical reaction.

Note that the reaction will not take place unless there is a complete circuit to allow two electrons to be supplied to the cathode. Under many circumstances, these electrons come from the anode, flow through a resistance, and return to the cathode. Note also that since the chemical reactions involve substances with resistance, it is not possible to create the emf without an internal resistance.

Figure 4.11 Artist’s conception of two electrons being forced onto the anode of a cell and two electrons being removed from the cathode of the cell. The chemical reaction in a lead-acid battery places two electrons on the anode and removes two from the cathode. It requires a closed circuit to proceed since the two electrons must be supplied to the cathode.

Why are the chemicals able to produce a unique potential difference? Quantum mechanical descriptions of molecules, which take into account the types of atoms and numbers of electrons in them, are able to predict the energy states they can have and the energies of reactions between them.

In the case of a lead-acid battery, an energy of 2 eV is given to each electron sent to the anode. Voltage is defined as the electrical potential energy divided by charge: $V=\frac{P_{\text{E}}}{q}\text{.}V=\frac{P_{\text{E}}}{q}\text{.}$ An electron volt is the energy given to a single electron by a voltage of 1 V. So the voltage here is 2 V since 2 eV is given to each electron. It is the energy produced in each molecular reaction that produces the voltage. A different reaction produces a different energy and, hence, a different voltage.

Terminal Voltage

The voltage output of a device is measured across its terminals and, thus, is called its terminal voltage$V$null Terminal voltage is given by

where null is the internal resistance and null is the current flowing at the time of the measurement.

null is positive if current flows away from the positive terminal, as shown in Figure 4.9. You can see that the larger the current, the smaller the terminal voltage. And it is likewise true that the larger the internal resistance, the smaller the terminal voltage.

Suppose a load resistance null is connected to a voltage source, as in Figure 4.12. Since the resistances are in series, the total resistance in the circuit is null Thus, the current is given by Ohm’s law to be

Figure 4.12 Schematic of a voltage source and its load null Since the internal resistance null is in series with the load, it can significantly affect the terminal voltage and current delivered to the load. (Note that the script E stands for emf.)

We see from this expression that the smaller the internal resistance null the greater the current the voltage source supplies to its load null As batteries are depleted, null increases. If null becomes a significant fraction of the load resistance, then the current is significantly reduced, as the following example illustrates.

Applying the Science Practices: Internal Resistance

The internal resistance of a battery can be estimated using a simple activity. The circuit shown in the figure below includes a resistor R in series with a battery along with an ammeter and voltmeter to measure the current and voltage, respectively.

Figure 4.13

The currents and voltages measured for several R values are shown in the table below. Using the data given in the table and applying graphical analysis, determine the emf and internal resistance of the battery. Your response should clearly explain the method used to obtain the result.

Resistance	Current (A)	Voltage (V)
RI	3.53	4.24
RII	2.07	4.97
RIII	1.46	5.27
RIV	1.13	5.43

Table 4.1

Answer

Plot the measured currents and voltages on a graph. The terminal voltage of a battery is equal to the emf of the battery minus the voltage drop across the internal resistance of the battery, or V = emf – Ir. Using this linear relationship and the plotted graph, the internal resistance and emf of the battery can be found. The graph for this case is shown below. The equation is V = –0.50I+6.0, and hence the internal resistance will be equal to 0.5 Ω and emf will be equal to 6 V.

Figure 4.14

Battery testers, such as those in Figure 4.15, use small load resistors to intentionally draw current to determine whether the terminal voltage drops below an acceptable level. They really test the internal resistance of the battery. If internal resistance is high, the battery is weak, as evidenced by its low terminal voltage.

Figure 4.15 These two battery testers measure terminal voltage under a load to determine the condition of a battery. The large device is being used by a U.S. Navy electronics technician to test large batteries aboard the aircraft carrier USS Nimitz and has a small resistance that can dissipate large amounts of power. (U.S. Navy photo by Photographer’s Mate Airman Jason A. Johnston) The small device is used on small batteries and has a digital display to indicate the acceptability of their terminal voltage. (Keith Williamson)

Some batteries can be recharged by passing a current through them in the direction opposite to the current they supply to a resistance. This is done routinely in cars and batteries for small electrical appliances and electronic devices and is represented pictorially in Figure 4.16. The voltage output of the battery charger must be greater than the emf of the battery to reverse current through it. This will cause the terminal voltage of the battery to be greater than the emf since null and null is now negative.

Figure 4.16 A car battery charger reverses the normal direction of current through a battery, reversing its chemical reaction and replenishing its chemical potential.

Multiple Voltage Sources

There are two voltage sources when a battery charger is used. Voltage sources connected in series are relatively simple. When voltage sources are in series, their internal resistances add and their emfs add algebraically (see Figure 4.17). Series connections of voltage sources are common—for example, in flashlights, toys, and other appliances. Usually, the cells are in series in order to produce a larger total emf.

But if the cells oppose one another, such as when one is put into an appliance backward, the total emf is less since it is the algebraic sum of the individual emfs.

A battery is a multiple connection of voltaic cells, as shown in Figure 4.18. The disadvantage of series connections of cells is that their internal resistances add. One of the authors once owned a 1957 car that had two 6-V batteries in series rather than a single 12-V battery. This arrangement produced a large internal resistance that caused him many problems in starting the engine.

Figure 4.17 A series connection of two voltage sources. The emfs (each labeled with a script E) and internal resistances add, giving a total emf of ${\text{emf}}_1+{\text{emf}}_2$ and a total internal resistance of $r_1+r_2\text{.}$

Figure 4.18 Batteries are multiple connections of individual cells, as shown in this modern rendition of an old print. Single cells, such as AA or C cells, are commonly called batteries, although this is technically incorrect.

If the series connection of two voltage sources is made into a complete circuit with the emfs in opposition, then a current of magnitude $I=\frac{\left({\text{emf}}_1–{\text{emf}}_2\right)}{r_1+r_2}$ flows. See Figure 4.19, for example, which shows a circuit exactly analogous to the battery charger discussed above. If two voltage sources in series with emfs in the same sense are connected to a load $R_{\text{load}}\text{,}$ as in Figure 4.20, then $I=\frac{\left({\text{emf}}_1+{\text{emf}}_2\right)}{r_1+r_2+R_{\text{load}}}$ flows.

Figure 4.19 These two voltage sources are connected in series with their emfs in opposition. Current flows in the direction of the greater emf and is limited to $I=\frac{\left({\text{emf}}_1-{\text{emf}}_2\right)}{r_1+r_2}$ by the sum of the internal resistances. (Note that each emf is represented by script E in the figure.) A battery charger connected to a battery is an example of such a connection. The charger must have a larger emf than the battery to reverse current through it.

Figure 4.20 This schematic represents a flashlight with two cells (voltage sources) and a single bulb (load resistance) in series. The current that flows is $I=\frac{\left({\text{emf}}_1+{\text{emf}}_2\right)}{r_1+r_2+R_{\text{load}}}\text{.}$ (Note that each emf is represented by script E in the figure.)

Figure 4.21 shows two voltage sources with identical emfs in parallel and connected to a load resistance. In this simple case, the total emf is the same as the individual emfs. But the total internal resistance is reduced since the internal resistances are in parallel. The parallel connection thus can produce a larger current.

Here, $I=\frac{\text{emf}}{\left(r_{\text{tot}}+R_{\text{load}}\right)}$ flows through the load, and $r_{\text{tot}}$ is less than those of the individual batteries. For example, some diesel-powered cars use two 12-V batteries in parallel; they produce a total emf of 12 V but can deliver the larger current needed to start a diesel engine.

Figure 4.21 Two voltage sources with identical emfs (each labeled by script E) connected in parallel produce the same emf but have a smaller total internal resistance than the individual sources. Parallel combinations are often used to deliver more current. Here, $I=\frac{\text{emf}}{\left(r_{\text{tot}}+R_{\text{load}}\right)}$ flows through the load.

Animals as Electrical Detectors

A number of animals both produce and detect electrical signals. Fish, sharks, platypuses, and echidnas (spiny anteaters) all detect electric fields generated by nerve activity in prey. Electric eels produce their own emf through biological cells (electric organs) called electroplaques, which are arranged in both series and parallel as a set of batteries.

Electroplaques are flat, disk-like cells; those of the electric eel have a voltage of 0.15 V across each one. These cells are usually located toward the head or tail of the animal, although in the case of the electric eel, they are found along the entire body. The electroplaques in the South American eel are arranged in 140 rows, with each row stretching horizontally along the body and containing 5,000 electroplaques. This can yield an emf of approximately 600 V and a current of 1 A—deadly.

The mechanism for detection of external electric fields is similar to that for producing nerve signals in the cell through depolarization and repolarization—the movement of ions across the cell membrane. Within the fish, weak electric fields in the water produce a current in a gel-filled canal that runs from the skin to sensing cells, producing a nerve signal. The Australian platypus, one of the very few mammals that lay eggs, can detect fields of 30 $\frac{\text{mV}}{\mathrm{m}}\text{,}$ while sharks have been found to be able to sense a field in their snouts as small as 100 $\frac{\text{mV}}{\mathrm{m}}$ (Figure 4.22). Electric eels use their own electric fields produced by the electroplaques to stun their prey or enemies.

Figure 4.22 Sand tiger sharks (Carcharias taurus), like this one at the Minnesota Zoo, use electroreceptors in their snouts to locate prey. (Jim Winstead, Flickr)

Solar Cell Arrays

Another example dealing with multiple voltage sources is that of combinations of solar cells—wired in both series and parallel combinations to yield a desired voltage and current. Photovoltaic generation (PV), the conversion of sunlight directly into electricity, is based on the photoelectric effect, in which photons hitting the surface of a solar cell create an electric current in the cell.

Most solar cells are made from pure silicon—either as single-crystal silicon or as a thin film of silicon deposited on a glass or metal backing. Most single cells have a voltage output of about 0.5 V, while the current output is a function of the amount of sunlight on the cell (the incident solar radiation—the insolation). Under bright noon sunlight, a current of about $\text{100}{\text{mA/cm}}^2$ of cell surface area is produced by typical single-crystal cells.

Individual solar cells are connected electrically in modules to meet electrical-energy needs. They can be wired together in series or in parallel—connected like the batteries discussed earlier. A solar-cell array or module usually consists of between 36 and 72 cells, with a power output of 50 to 140 W.

The output of the solar cells is direct current. For most uses in a home, AC is required, so a device called an inverter must be used to convert the DC to AC. Any extra output can then be passed on to the outside electrical grid for sale to the utility.